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Metal-organic frameworks (MOFs) are a class of highly ordered crystalline porous coordination polymers (PCPs). MOFs have the advantages of clear structure, high specific surface area and porosity, adjustable pore size, and easy chemical functionalization. They are considered to be a class of promising nano-medicine carriers. In recent years, the research of metal-organic framework (MOF) for biomedicine has attracted much attention.

2. Covalent Organic Framework (COF) is a type of crystalline organic porous material that has received a lot of attention. It has important application prospects in the fields of gas storage, gas separation, catalysis, sensors, and photoelectric response devices. However, compared with the above-mentioned fields, the application of COF in the field of biomedicine is relatively rare. In fact, COF is a good carrier for loading small molecule drugs or diagnostics due to its porosity and excellent structural stability, but how to quickly release the small molecules loaded in COF is still an unsolved problem. On the other hand, for photodynamic therapy (PDT), due to the short diffusion distance of singlet oxygen (about 20 nm), the release and diffusion of photosensitizers in cells will seriously affect the efficacy of PDT.

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3. Hydrogel is a three-dimensional network structure formed by cross-linking of water-soluble polymers through physical or chemical action. Due to the existence of cross-linked structure, hydrogel can absorb water and swell without dissolving. Smart hydrogel refers to a special hydrogel that can produce rapid changes in the volume of the gel or other physical and chemical properties according to environmental changes or external stimuli, so it is also called environmentally sensitive hydrogel. Smart hydrogels have shown great development potential in the fields of biosensors, biomedicine, molecular devices, and drug carriers.