HOF-102
| 【Numbering】BK2021013009 | 【CAS】CAS | ||
| 【Item No.】BK2021012346 | 【specification】 | ||
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Other name: HOF-102
CAS: NA
Structure information
Unit molecular formula C60H34O8 Unit molecular weight 882.90716
Monomer structure 6,60,600,600 0-(Pyrene-1,3,6,8-tetrayl)tetrakis(2-naphthoic acid) / H4PTTNA (CAS: 2010983-66-9)
Pore size 3.0nm, 2.5nm; layer spacing 3.65-3.71nm pore volume 1.35 cm3/g
Specific surface BET specific surface 2500 m2/g
Analog structure
产品性状
产品形貌 黄色粉末
Yellow Powder
粒径
稳定性
1) HOF-14/HOF-102是最稳定的有机多孔材料之一
2) 空气中持久稳定，水溶液甚至沸水中稳定，在酸性和碱性溶液（PH 1-14）中稳定
2) 高热稳定性、热分解温度大于 400℃
保存和活化方法
1) 常温或低温条件下，干燥密封保存
2) 建议使用前120度（真空）活化6小时
其他特性
NA
应用领域
1) 稳定的骨架结构可储气材料和吸附材料
2) 2.5-3.1nm的较大孔径可吸附一些较大的分子离子、药物、酶和RNA等大分子，尤其适用于酶固定。
3) HOF-102 易于和纺织纤维复合，用于柔性器件和传感器开发
表征图谱
references
1) Ma, K.; Li, P.; Xin, J.; Chen, Y.; Chen, Z.; Goswami, S.; Liu, X.; Kato, S.; Chen, H.; Zhang, X .; Bai, J.; Wasson, Me.; Maldonado, R.; Snurr, R.; Farha; O.; Cell Reports Physical Science 2020, 1, 100024, DOI:10.1016/j.xcrp.2020.100024; Ultrastable Mesoporous Hydrogen -Bonded Or-ganic Frameworks Based Fiber Composites To-ward Mustard Gas Detoxification
2) Wang, B.; Lv, X.; Lv, J.; Ma, L.; Lin, R.; Cui, H.; Zhang, J.; Zhang, Z.; Xiang, S.; Chen, B .; Chem. Commun., 2020, 56, 66-69, DOI: 10.1039/c9cc07802a; A novel mesoporous hydrogen-bonded organic framework with high porosity and stability
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